The verdict
For a small B2B or service team, I'd pick Keap. It is a CRM with payments, and Postscript is built for Shopify stores, not service businesses.
If you sell on Shopify and want SMS to carry real revenue, I'd pick Postscript. Its compliance support and opt-in tools are the reason to choose it over an email tool with SMS added.
The pricing shapes differ. Keap has a single plan priced by contact count and an early termination fee on annual contracts. Postscript bills by message with carrier fees on their own line, so a busy sale week costs more than a quiet one. Model a normal period and a peak period before you commit to either.